Ozone in Urban WWTP

Ozone in Waste Water Treatment Station

Use of Ozone in Urban WWTP


Internal Reference: AGUA_EDAR

Use of Ozone in Urban WWTP

Ozone is a well-established technology in Urban WWTPs. There are four main application stages: 

Pre-oxidation of the flow before the biological stage, to improve the COD/BOD ratio.  Recirculated Sludge Treatment, to improve the sludge volumetric index.  Tertiary Treatment, for disinfection and reuse.  Quaternary Treatment, for the removal of emerging contaminants.

The powerful oxidation capacity of ozone makes it an excellent tool for working in any of these stages, as it has a direct benefit on COD, BOD, SS, SD, turbidity, color, odor, emerging contaminants, and, of course, microbiology. Ozone is a simple and safe technique that achieves the most demanding results.


ZonoSistem provides detailed engineering consulting for project drafting, in addition to designing and manufacturing ozone generators for real-world applications.

IImprove the discharge parameters of your WWTP 
and promotes the reuse of water

Avoid the use of chlorine and packaged chemicals

Ozone is generated on-site, eliminating the need to store or transport chemicals

Ozone leaves no residues, is environmentally friendly, and reduces the carbon footprint

The system is automated and does not require labor for application


Do you want to improve the performance of your Urban WWTP?

Toxicity issues in the biological stage?

Filamentous sludge problems?

Trouble meeting discharge parameters?

Want to reduce sludge? 

Issues with byproducts of traditional chemicals?

Want to reuse water according to the new reuse regulation (RD 1085/2024)?

Improve wastewater performance

Ozone Phases in WWTP

Pre-oxidation before the biological flow

Pre-oxidation of the flow before the biological stage

The application of ozone prior to the biological reactor improves its performance. Ozone oxidizes detergents, polyphenols, and other compounds that affect the COD/BOD ratio. Additionally, O3 increases the dissolved oxygen rate. It is especially recommended for urban WWTPs as they receive industrial wastewater.

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Recirculating Sludge Treatment

The application of ozone improves the sludge volumetric index, reducing Escherichia coli in suspended solids in the decanted effluent, volatile matter in mixed liquor, and overall reducing sludge and its management.

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Tertiary and Quaternary Treatment

The application of ozone in Tertiary Treatment aims at water disinfection and reuse. On the other hand, ozone in Quaternary Treatment has the ability to eliminate emerging contaminants.

Advantages of Treating WWTP with Ozone

Without labor, automatic

The system generates ozone and injects it into the tank automatically, without the need to apply manual labor in the process. The equipment only needs to be connected to the tank to be treated and provide it with a point of light.

No chemical storage

Ozone cannot be transported or stored; it is generated on-site and applied instantly, eliminating the need for chemical storage and management, avoiding transportation, and reducing the carbon footprint.

Agent recognized by the ECHA

Ozone is listed as a biocide by the European Chemicals Agency, and ZonoSistem has all the necessary legal documentation for ozone application in your process.

Ranges of Ozone Generators Available for WWTPs

Next, we show you the ranges of ozone generators available to treat urban wastewater WWTP
 
 Gama Generador de ozono industrial
Gama Generador de ozono profesional

Gama Generador de ozono profesional
RecommendationsOzone equipment from 5 to 150 kgO3/h For LOX feeding, liquid oxygen.

Ozone equipment from 5 to 150 kgO3/h For LOX feeding, liquid oxygen.

Ozone equipment from 80 to 500 kgO3/h Includes complete air unit (Compressor + PSA).
Equipment Included
Generation Ferrule, Borosilicate Dielectric.
Water Cooled Generator.
Transformer and electrical panel.
With Automatic Power Control.
With Recipe manager by PLC.
With Leak Sensor.
Generation Ferrule.
Borosilicate or Ceramic Dielectric.
Water Cooled Generator.
Transformer and electrical panel.
With Automatic Power Control.
With Recipe manager by PLC.
With Leak Sensor.
Generation Ferrule, Borosilicate Dielectric.
Water Cooled Generator.
Transformer and electrical panel.
With Automatic Power Control.
With Recipe manager by PLC.
With Leak Sensor.
With Oxygen Compressor and Concentrator.
With Integrated Cooler.
Optional equipment
Ozone gas meter.
Cooling system.
Dosing system.
Ozone destruction system.
Sub-over valves.
Ozone gas meter.
Cooling system.
Dosing system.
Ozone destruction system.
Sub-over valves.
Ozone gas meter.
Ozone destruction system.
Sub-over valves.
Ozone concentration
150 gO3/m 
150 gO3/m3
150 gO3/m3
Ozone Productions
From 80 to 5.000 gO3/hFrom 5 to 150 kgO3/hFrom 80 to 500 gO3/h
Working conditions
1 bar1 bar1 bar

1. What is the difference between the ranges?

The GR and GRV ozone generator ranges are designed to be powered with LOX oxygen. They are industrial-grade, robust units with high ozone concentration, designed and manufactured with care to operate 24/7. The GR range covers up to 1 kg O₃/h, featuring ceramic dielectric technology, while the GRV range is intended for higher production, up to 40 kg O₃/h.

On the other hand, the GRZO range differs from the other two because it comes with an integrated compressor and oxygen concentrator, so it doesn't require LOX oxygen. It is an autonomous unit that only needs electricity. It is also an industrial-grade system with high performance and efficiency.

2. Which range do you recommend?

The first thing is to calculate the amount of ozone you need. If you need more than 1Kg or 3/h, you will have to select the GRV range. For productions less than 1KgO3/h, you have the GRZO version, with compressor and oxygen concentrator, and if you prefer to work with LOX oxygen supply, you have the GR range. I recommend using the GRZO range whenever possible, it is a bit more expensive but you avoid the costs of LOX oxygen. 

3. How much ozone do I need?

A different amount of ozone is required for each stage in a WWTP. Generally, for pre-oxidation of the flow before the biological stage, ozone doses between 1 and 5 ppm are applied to the treated flow. In sludge treatment, doses range between 5 and 10 ppm, while for tertiary and quaternary treatment, ozone doses range between 8 and 10 ppm.

Water Pilot Testing

Before making the investment, we recommend conducting a water pilot test in our testing laboratory. We can calculate the required ozone doses and contact times, thus assessing the feasibility of the treatment.

Contact now
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Example of Ozone Installations in WWTPs

WWTP in Saudi Arabia.

WWTP in Saudi Arabia.

Urban WWTP in Morocco.

Urban WWTP in Morocco.

WWTP Pre-oxidation in Tenerife.

WWTP Pre-oxidation in Tenerife.

Tertiary WWTP in Manacor.

Tertiary WWTP in Manacor.

WWTP Pre-oxidation in the Valencian Community.

WWTP Pre-oxidation in the Valencian Community.

Intermediate Sludge Treatment.

Intermediate Sludge Treatment. Urban WWTP Comunidad Valenciana.

Do you need a quotation?